Preliminary Contamination Risk Assessment of Mining Waste Using Spatial Analysis and Geochemical Characterization of Rock Formations. Case Study in Hungary
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Abstract
The Mine Waste Directive (2006/21/EC) requires the risk-based inventory of all mine waste sites in Europe. The geochemical documentation concerning inert classification and ranking of the mine wastes requires specific field study and laboratory testing and analyses of waste material to assess the Acid Mine Drainage potential and toxic element mobility. The procedure applied in this study used a multi-level decision support scheme for the inert classification of waste rock material including: 1) expert judgment, 2) data review, 3) representative field sampling and laboratory analysis and testing of rock formations listed in the National Inert Mining Waste List, and 4) requesting available laboratory analysis data from selected operating mines. Based on a preliminary expert judgment, the listed formations were classified into three categories. A: inert B: probably inert, but has to be checked, C: probably not inert, has to be examined. This paper discusses the heavy metal contamination risk assessment (RA) in the Hungarian quarrymine waste sites. In total 30 waste sites (including both abandoned mines and active quarries) were selected for scientific testing using the EU Pre-selection Protocol. Altogether 93 field samples were collected from the waste sites including andesite, rhyolite, coal (lignite and black coals), peat, alginite, bauxite, clay and limestone. Laboratory analyses of the total toxic element content (aqua regia extraction), the mobile toxic element content (deionized water leaching) carried out according to the Hungarian GKM Decree No. 14/2008. (IV.3) concerning mining waste management. A detailed geochemical study together with spatial analysis and GIS were performed to derive a geochemically sound contamination RA of the mine waste sites. Key parameters such as heavy metals, in addition to the landscape metric parameter such as the distance to the nearest surface and ground water bodies, or to sensitive receptors such as settlements and protected areas calculated and statistically evaluated in order to calibrate the RA methods. Results show that some of the waste rock materials, assumed to be inert, were found non-inert. Thus, regional RA needs more spatial and petrological examination with special care to rock and mineral deposit genetics.
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Abdaal, A., Jordan, G., Szilassi, P. 2013. Testing Contamination Risk Assessment Methods for Mine Waste Sites. Water, Air, & Soil Pollution 224,1416. DOI: 10.1007/s11270-012-1416-x
BAT, 2003. Draft Reference Document on Best Available Techniques for Management of Tailings and Waste-Rock in Mining Activities, 2003. European IPPC Bureau, Joint Research Centre of the European Commission, Seville.
Charman, D. 2002. Peatlands and environmental change. J. Wiley & Sons, London & New York, 301 p.
COM 2003, 319 final. Proposal for a Directive of the European Parliament and of the Council on the Management of Waste from the Extractive Industries. COM(2003) 319 final, 2003/0107 (COD), Commission of the European Communities, Brussels.
COM 2005, 670 final. Communication from the Commission to the Council, the European Parliament, the European Economic and Social Committee and the Committee of the Regions - Thematic Strategy on the sustainable use of natural resources.
COM 2006, 231 final. Communication from the Commission to the Council, the European Parliament, the European Economic and Social Committee and the Committee of the Regions - Thematic Strategy for Soil Protection [SEC(2006)620] [SEC(2006)1165]. http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=CELEX:52006DC0231:EN:NOT
Del-Rio, J.C., Gonzalez-Vila, F.J., Martin, F. 1992. Variation in the content and distribution of biomarkers in two closely situated peat and lignite deposits. Organic Geochemistry. 18(1), 67-78. DOI: 10.1016/0146-6380(92)90144-M
Directive 2006/21/EC the European Parliament and of the Council on the management of waste from extractive industries and amending Directive 2004/35/EC. Commission of the European Communities, Brussels. http://eurlex.europa.eu/LexUriServ/LexUriServ.do?uri=CONSLEG:2006L0021:20090807:EN:PDF
EEA, European Environment Agency. 2007. Progress in the management of contaminated sites (CSI 015) - assessment published in August 2007.
EEA, European Environment Agency. 2005. Towards an EEA Europewide assessment of areas under risk for soil contamination, Vol. 2. Review and analysis of existing methodologies for preliminary risk assessment. http://sia.eionet.europa.eu/activities/reportste/PRAMS2
Gömöryová, E., Vass, D., Pichler, V., Gömöry, D. 2009. Effect of alginite amendment on microbial activity and soil water content in forest soils. Biologia 64(3), 585-588. DOI: 10.2478/s11756-009-0081-z
Hamor-Vido, M. 2004. Coal facies studies in Hungary: a historical review. International Journal of Coal Geology 58, 91-97. DOI:10.1016/j.coal.2003.05.003
Hungarian GKM Decree No. 14/2008. (IV. 3) concerning mining waste management. http://www.mbfh.hu/gcpdocs/201107/gkm_ministry_of_economy_and_transport_decree_no_14_2008_iv_3_on_minig_waste_management.pdf
International Organization for Standardization 1995. ISO 11466 International standard Soil quality -extraction of trace elements soluble in aqua regia. 03-01.
Jordan, G. 2004. Mining and mining waste: pressures, impacts and responses in the enlarged European Union. In: Jordan G, D’Alessandro M. (eds) Mining, mining waste and related environmental issues: problems and solutions in the Central and Eastern European candidate countries. Joint Research Centre of the European Commission, Ispra. LB-NA-20868-EN-C, 13-34.
Jordan, G., D’Alessandro, M. (eds). 2004. Mining, mining waste and related environmental issues: problems and solutions in the Central and Eastern European candidate countries. Joint Research Centre of the European Commission, Ispra. LB-NA-20868-ENC.
Jordan, G., Fügedi, U., Bartha, A., Vatai, J., Tóth, G., Murati, J., Szentpéteri, I., Konya, P., Gaburi, I., Tolmács, D., Müller, T. 2011. The red mud catastrophe in Kolontár Hungary: applying geology. European Geologist 32, 9-13.
Kavouridis. K., Koukouzas, N. 2008. Coal and sustainable energy supply challenges and barriers. Energy Policy 36, 693-703. DOI:10.1016/j.enpol.2007.10.013
Lei, L.., Song, C.., Xie, X.., Li, Y., Wang, F,. 2010. Acid mine drainage and heavy metal contamination in groundwater of metal sulfide mine at arid territory (BS mine, Western Australia). Transactions of Nonferrous Metals Society of China 20, 1488-1493.
Long, J., Fischhoff, B. 2000. Setting risk priorities: a formal model. Risk Analysis 20, 339-352. DOI: 10.1111/0272-4332.203033
Luo, W., Lu, Y., Zhang, Y., Fu, W.,Wang, B., Jiao, W.,Wang, G.,Tong, X.,Giesy, J. P. 2010. Watershed-scale assessment of arsenic and metal contamination in the surface soils surrounding Miyun Reservoir, Beijing, China. Journal of Environmental Management 91, 2599-2607. DOI:10.1016/j.jenvman.2010.07.023
Marcomini, A., Suter II, G. W., Critto, A. 2009. Decision support systems for risk based management of contaminated sites. New York: Springer Verlag.
Navarro, M. C., Pérez-Sirvent, C., Martínez-Sánchez, M. J., Vidal, J., Tovar, P. J., Bech, J. 2008. Abandoned mine sites as a source of contamination by heavy metals: A case study in a semi-arid zone. Journal of Geochemical Exploration 96, 183-193. DOI:10.1016/j.gexplo.2007.04.011
Panagopoulos, I., Karayannis, A., Adamb, K., Aravossis, K. 2009. Application of risk management techniques for the remediation of an old mining site in Greece. Waste Management 29, 1739-1746. DOI: 10.1016/j.wasman.2008.11.017
Peplow, D., Edmonds, R. 2005. The effects of mine waste contamination at multiple levels of biological organization. Ecological Engineering 24, 101-119. DOI:10.1016/j.ecoleng.2004.12.011
Perger A. 2009. The role of coal in the Hungarian electricity sector. Short overview on the use of coal in the electricity sector. Energiaklub. http://energiaklub.hu/en/publication/the-role-of-coal-inthe-hungarian-electricity-sector
Plumlee, G.S., Smith, K.S., Montour, M.R., Ficklin, W.H., and E.L. Mosier, 1999. Geologic Controls on the Composition of Natural Waters and Mine Waters Draining Diverse Mineral-Deposit Types. In: L.H. Filipek and G.S. Plumlee (Eds.), The Environmental Geochemistry of Mineral Deposits, Part B: Case Studies and Research Topics, Reviews in Economic Geology Vol. 6B, Society of Economic Geologists, 373-432.
Puura E., Marmo L. and D’Alessandro M. (eds), 2002. Proceedings of the Workshop on Mine and Quarry Waste - the Burden from the Past. Joint Research Centre of the European Commission, Ispra.
Szabo, L.P. 2004. Characterization of alginite humic acid content. Desalination, 163, 85-91. DOI: 10.1016/S0011-9164(04)90180-4
Sarmiento, A. M., DelValls, A., Nieto, J. M., Salamanca, M. J., Caraballo, M.A. 2011. Toxicity and potential risk assessment of a river polluted by acid mine drainage in the Iberian Pyrite Belt (SW Spain). Science of the Total Environment 409, 4763-4771. DOI: 10.1016/j.scitotenv.2011.07.043
Sinding K., 1999. Environmental impact assessment and management in the mining industry. Natural Resources Forum, 23, 57-63. DOI: 10.1111/j.1477-8947.1999.tb00238.x Spedding, P.J. 1988. Peat, review. Fuel 67, 883-900. DOI: 10.1016/0016-2361(88)90087-7
Stanley, G., Jordan, G., Hamor, T., Sponar, M. 2011. Guidance Document for A Risk-Based Selection Protocol for the Inventory of Closed Waste Facilities as required by Article 20 of Directive 2006/21/EC. February, 2011. http://www.geofond.cz/rroum/dokument/2011_GUIDANCE_DOCUMENT_PRE_SELECTION.pdf
Steinmann, P., Shotyk, W. 1997. Geochemistry, mineralogy, and geochemical mass balance on major elements in two peat bog profiles (Jura Mountains, Switzerland). Chemical Geology 138, 25-53. DOI:10.1016/S0009-2541(96)00171-4
Szabo, L.P. 2004. Characterization of alginite humic acid content. Desalination 163, 85-91. DOI:10.1016/S0011-9164(04)90180-4
U.S. EPA. 2001. Abandoned mine site characterisation and cleanup handbook. Denver. EPA530-C-01-001. http://www.epa.gov/superfund/policy/remedy/pdfs/amscch.pdf
Vass, D., Bublinec, E., Halás, L., Beláček, B. 2003. Overview of Pinciná alginite fertility. Földtani Kutatás 15, 75-80.
Younger P. L., Banwart S. A. and Hedin R. S., 2002. Mine Water. Hydrology, Pollution, Remediation. Kluwer Academic Publishers, Dodrecht.
Hungarian Central Statistical Office. www.ksh.hu
Hungarian Central Directorate of Water and Environment (VKKI). http://www.vkki.hEEAwebsite/Dataandmaps/Datasets/Waterbase-Groundwater. http://www.eea.europa.eu/data-and-maps/data/waterbasegroundwater-6
CORINE Land Cover datasets. http://www.eea.europa.eu/publications/COR0-landcover