Influence of synthesis on composite/laminated starch-gelatine based biopolymer film properties

Authors

DOI:

https://doi.org/10.14232/analecta.2022.1.50-55

Abstract

Biopolymer films have an increasing share in the packaging material sector due to a number of advantages: availability, cheapness, easy processing, degradability, etc. On the other hand, numerous methods have been developed to optimize their unfavorable properties (weaker mechanical characteristics, hydrophilicity, etc.). This paper examines the influence of the synthesis method on starch-gelatin films properties. The starch-gelatin film was synthesized in a ratio 1:1 as a composite film (C). The second sample was obtained by gelatin film lamination on starch film (L). Plain starch film was used as a control (0). Mechanical, structural and physico-chemical properties of importance for the application of packaging materials were tested on the obtained samples. All the obtained biopolymer films were transparent and easy to handle. FTIR spectroscopy identified all characteristic groups and bonds formed in composite and laminated films. The results showed a significant contribution of gelatin in the developed biopolymer films compared to the control sample. Gelatin incorporated as a film component or as a separate layer improved mechanical properties and water solubility. Slight differences were observed between composite and laminated films because the effect of the method of added gelatin is minimal compared to the sample without the addition of gelatin.

Downloads

Download data is not yet available.

References

T. Schwarzbock, E. Van Eygen, H. Rechberger, J. Fellner, Determining the amount of waste plastics in the feed of Austrian waste-to-energy facilities, Waste Management & Research, 35 (2016), pp. 207–216. https://doi.org/10.1177/0734242X16660372.

A., Moeini, N., Germann, M., Malinconico, G., Santagata, Formulation of secondary compounds as additives of biopolymer-based food packaging: A review, Trends in Food Science & Technology, 114 (2021), pp. 342-354. https://doi.org/10.1016/j.tifs.2021.05.040.

Y. Han, M., Yu, L., Wang, Physical and antimicrobial properties of sodium alginate/carboxymethyl cellulose films incorporated with cinnamon essential oil, Food Packaging and Shelf Life, 15 (2018), pp. 35–42. https://doi.org/10.1016/j.fpsl.2017.11.001.

M.J., Fabra, A., López-Rubio, J.N., Lagaron, Biopolymers for food packaging applications. In: Smart Polymers and their Application. Elsevier, 2014, pp. 476–509. https://doi.org/10.1533/9780857097026.2.476.

S., Popović, V., Lazić, N., Hromiš, D., Šuput, S., Bulut, Biopolymer packaging materials for food shelf-life prolongation. In: Biopolymers for food design, Academic Press, Elsevier, 2018, pp. 223-277 https://doi.org/10.1016/B978-0-12-811449-0.00008-6.

D., Šuput, V., Lazić, S., Popović, N., Hromiš, Edible films and coatings – sources, properties and application, Food and Feed Research, 42 (2015), pp.11-22. https://doi.org/10.5937/FFR1501011S.

D., Šuput, D. Sinteza, karakterizacija, optimizacija svojstava i primena jestivog, aktivnog ambalažnog materijala na bazi skroba. PhD Thesis, University of Novi Sad, Faculty of Technology Novi Sad, 2016.

D. Kowalczyk M., Kordowska-Wiater J., Nowak, B., Baraniak, Characterization of films based on chitosan lactate and its blends with oxidized starch and gelatin, International Journal of Biological Macromolecules, 77 (2015), pp. 350–359. https://doi.org/10.1016/j.ijbiomac.2015.03.032.

P., Cazón, G., Velazquez, J.A., Ramírez, M., Vázquez, Polysaccharide-based films and coatings for food packaging: A review, Food Hydrocolloids, 68 (2017), pp. 136–148. https://doi.org/10.1016/j.foodhyd.2016.09.009.

L., Lin, J.M., Regenstein, S., Lv, J., Lu, S., Jiang, An overview of gelatin derived from aquatic animals: properties and modification, Trends in Food Science and Technology, 68 (2017), pp.102–112. https://doi.org/10.1016/j.tifs.2017.08.012

N., Suderman, M.I.N., Isa, N.M., Sarbon, The effect of plasticizers on the functional properties of biodegradable gelatin-based film: a review, Food Bioscience, 24 (2018), pp. 111–119. https://doi.org/10.1016/j.fbio.2018.06.006.

C. Shi, F., Tao, Y., Cui, New starch ester/gelatin-based films: developed and physicochemical characterization, International Journal of Biological Macromolecules, 109 (2018), pp. 863–887. https://doi.org/10.1016/j.ijbiomac.2017.11.073 .

N., Jabeen, I., Majid, G.A., Nayik, Bioplastics and food packaging: A review, Cogent Food & Agriculture, 1 (2015), pp. 1117749. https://doi.org/10.1080/23311932.2015.1117749.

B.A.L., Perez, E., Agama-Acevedo, E. Starch. In Starch-Based Materials in Food Packaging. Elsevier, (2017), pp. 1–18. https://doi.org/10.1016/b978-0-12-809439-6.00001-7.

K., Mahmood, H., Kamilah, P.L., Shang, S., Sulaiman, F., Ariffin, A.K., Alias, A review: interaction of starch/non-starch hydrocolloid blending and the recent food applications, Food Bioscience, 19 (2017), pp.110–120. https://doi.org/10.1016/j.fbio.2017.05.006.

K., Wang, W., Wang, R., Ye, J., Xiao, Y., Liu, J., Ding, J., et al., Mechanical and barrier properties of maize starch - gelatin composite films: Effects of amylose content, Journal of the Science of Food and Agriculture, 97 (2017), pp.3613–3622. https://doi.org/10.1002/jsfa.8220.

N.M., Silva, F.M., Fakhouri R.L.L., Fialho, E.C.D.M.A., Albuquerque, Starch-recycled gelatin composite films produced by extrusion: physical and mechanical properties, Journal of Applied Polymer Science, 135 (2018), pp.46254. https://doi.org/10.1002/app.46254.

A.A., Al-Hassan, M.H., Norziah, Effect of transglutaminase induced crosslinking on the properties of starch/gelatin films, Food Packaging and Shelf Life, 13 (2017), pp.15–19. https://doi.org/10.1016/j.fpsl.2017.04.006.

F.M., Fakhoury, S.M., Martelli, L.C., Bertan, F., Yamashita, L.H.I., Mei, F.P.C., Queiroz, Edible films made from blends of manioc starch and gelatin – influence of different types of plasticizer and different levels of macromolecules on their properties, LWT 49 (2012), pp.149–154. https://doi.org/10.1016/j.lwt.2012.04.017.

S., Acosta, A., Jiménez, M., Cháfer, C., González-Martínez, A., Chiralt, Physical properties and stability of starch–gelatin-based films as affected by the addition of esters of fatty acids, Food Hydrocolloids, 49 (2015), pp. 135–143. https://doi.org/10.1016/j.foodhyd.2015.03.015.

Downloads

Published

2022-08-05

How to Cite

Šuput, D., Popović, S., Ugarković, J., & Hromiš, N. (2022). Influence of synthesis on composite/laminated starch-gelatine based biopolymer film properties. Analecta Technica Szegedinensia, 16(1), 50–55. https://doi.org/10.14232/analecta.2022.1.50-55

Issue

Section

Articles

Funding data

Most read articles by the same author(s)